Abstract
This paper presents the changes in microstructure and mechanical properties that occurred across the wall cross-section of a massive slag ladle casting due to service conditions. The slag ladle was made of low-carbon cast steel. Based on the test results, it was shown that the working environment influenced the macro-segregation of C and S on the cross-section of the wall and, consequently, had an effect on the changes in microstructure. A pearlitic-ferritic microstructure was found in the central part, while in the outer and inner parts of the wall, the microstructure was of a ferritic-pearlitic type. This change mainly influenced the impact energy-the lowest values were obtained at the centre of the wall (24 J at +20 °C). In the remaining areas tested on the wall cross-section at +20 °C, the impact energy exceeded the minimum required value of 27 J in the Charpy test. The tests revealed the presence of a network of cracks in areas adjacent to the inner surface of the ladle wall, which had a negative impact on the impact energy values, as did the presence of non-metallic inclusions. The changes found in the microstructure as a result of the ladle operation caused significant differences in properties such as impact energy and hardness, while also affecting, though to a lesser extent, the mechanical properties (UTS = 397-434 MPa; YS = 222-236 MPa).