Abstract
3,3-Bis (azide methyl) oxy-butyl ring (BAMO)-tetrahydrofuran (THF) copolyethers (PBT) are some of the most promising energetic binders. In this paper, the methods of synthesis of PBT binders are reviewed, and the research progress in PBT binders and PBT-based solid propellants in terms of their thermal and combustion behavior, curing and rheology properties, energy and aging properties, and mechanical and safety performances are systematically summarized. The problems and shortcomings of PBT binders in the application of solid propellants and their thriving trends are pointed out, providing support for speeding up the practical application of PBT binders in high-energy solid propellants.