Metal-Organic Framework (MOF)-Embedded Magnetic Polysaccharide Hydrogel Beads as Efficient Adsorbents for Malachite Green Removal

金属有机框架(MOF)包覆的磁性多糖水凝胶珠作为高效吸附剂用于去除孔雀石绿

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Abstract

Sodium alginate is a polysaccharide compound extracted from natural plants that has been successfully prepared as a hydrogel for adsorbing and removing pollutants. However, the selectivity of alginate-based hydrogels to malachite green (MG) dyes and the stability of alginate-based hydrogels in air cannot meet requirements. Herein, metal-organic frameworks (MOFs) are embedded into a magnetic hydrogel to create magnetic MOF hydrogel (MMOF hydrogel) microspheres with high adsorption capacity. The morphology and physical properties of the MMOF hydrogel microspheres were characterized by scanning electron microscopy and optical microscopy. Under optimized adsorption conditions, the adsorption rate of MG reached 96.5%. The maximum adsorption capacity of the MMOF hydrogel for MG was determined to be 315 mg·g(-1). This highly efficient magnetic adsorbent for dye removal has considerable potential for rapidly removing toxic contaminants from aquatic food matrices for high-throughput sampling pretreatment, which has the potential for rapid, green, large-scale environmental remediation in the future.

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