CFD comparison of novel [emim][DCA] and [emim][MS] ionic liquids for the separation of CO2 greenhouse gas in the membrane contactor

利用CFD方法比较新型[emim][DCA]和[emim][MS]离子液体在膜接触器中分离CO2温室气体的性能

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Abstract

Global warming (resulted by the abnormal emission of CO(2)) has recently been an important global subject of concern due to its detrimental effects on the human well-being. Therefore, developing novel and cost-effective procedure for mitigating the CO(2) release into the atmosphere is of prime importance. Recently, the employment of ionic liquids (ILs) for increasing the removal proficiency of CO(2) in membrane-based processes has been a hot research topic among scientists. The emergence of indisputable positive points such as eco-friendliness, low flammability and negligible volatility have made the ILs a promising alternative for benchmark amine solutions. In this paper, the authors have made their effort to propose a numerical model following to a computational fluid dynamics (CFD) simulation for estimating the separation percentage of CO(2) pollutant using 1-ethyl-3-methylimidazolium dicyanamide ([emim][DCA]) and 1-ethyl-3-methylimidazolium methylsulfate ([emim][MS]) ILs in the hollow fiber membrane contactor (HFMC). Comparison of model outcomes with experimental-based results shows an appropriate agreement with absolute relative error (ARE) less than 5%.

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