Integrating Experimental Crystallization Kinetics into Autodesk Moldflow: Validation and Crystallinity Prediction for iPP and POM

将实验结晶动力学集成到 Autodesk Moldflow 中:iPP 和 POM 的验证和结晶度预测

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Abstract

An accurate prediction of the final properties of injection-molded semi-crystalline parts requires models that capture crystallization kinetics during processing. This work presents two practical strategies to incorporate experimentally derived crystallization behaviors into Autodesk Moldflow, addressing cases where kinetics differ from the software's native Avrami-Hoffman-Lauritzen formulation. We apply these methods to isotactic polypropylene (iPP T30G) displaying heterogeneous nucleation with a low-temperature plateau, and to polyoxymethylene (POM) exhibiting combined heterogeneous and homogeneous nucleation. The parameters for Moldflow were obtained by matching isothermal half-crystallization times (t(0.5)) and by tuning flow-induced nucleation terms. Validation against isothermal and non-isothermal injection tests shows agreement between calculated and expected crystallinity evolution and reproduces measured spherulite diameters.

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