Abstract
The ballistic performance of fiber-reinforced polymer composites (FRPC) is influenced by the adhesive's mechanical properties, such as stiffness, toughness, and energy dissipation. However, the specific contributions of these properties remain unclear. This study explores how varying the hard segment (HS) content in water-based polyurethane (WPU) impacts the thermal, mechanical, and ballistic performance of FRPCs. By increasing HS content, the storage modulus and tensile strength of WPU improved, while elongation at break decreased, transitioning the adhesive from soft and ductile to rigid and brittle. Quasi-static tests, ballistic experiments, and SEM analysis were conducted on UHMWPE fiber-reinforced WPU-HS% composites. Results reveal that adhesives with high hardness and modulus hinder fiber deformation, reducing energy dissipation and causing severe delamination, which diminishes ballistic performance. Conversely, soft and ductile adhesives allow deformation alongside fibers during bullet impact, suppress delamination, and absorb more kinetic energy while transferring load. Among the tested formulations, WPU with 45% HS content exhibited the best balance of mechanical properties, achieving the most significant improvement in ballistic performance by enhancing energy absorption and minimizing damage. This study establishes a clear relationship between WPU properties and composite protective behavior, providing insights for designing high-performance ballistic materials.