Preparation and Evaluation of MXene/Graphene-Integrated Cellulose Aerogel Composite for Self-Heating Thermoregulation in Athletic Warm-Up Optimization

制备和评价MXene/石墨烯复合纤维素气凝胶材料在运动热身优化中的自加热体温调节应用

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Abstract

A warm-up is a critical procedure in sports science for enhancing muscular performance and optimizing subsequent athletic activities. However, the physiological and athletic performance effects of a warm-up are often transient, diminishing rapidly during the period of inactivity after the warm-up, which is known as the warm-up transition phase. In this study, a multi-functional thermoregulation wearable composite film of graphene-MXene-bacterial cellulose/polyethylene glycol (G-M-BC/PEG) was developed by integrating MXene (a two-dimensional material with good photothermal conversion performance) and graphene into a bacterial cellulose aerogel framework, subsequently impregnated with polyethylene glycol (PEG-2000). The film showed stable structure, efficient solar photothermal conversion and storage (SPCS), and improved mechanical properties. Under 1 sun irradiation, the optimized G-M-BC/PEG wearable film showed excellent SPCS performance, sustaining a temperature plateau of 38-40 °C for 10 min after the xenon lamp was switched off under 1 sun irradiation, with a leakage rate of only 5.32% after five cycles. By constructing a biomimetic sports human body model, the composite aerogel was shown to significantly elevate muscle surface temperature and effectively mitigate heat loss during the transition phase. In the warm-up effectiveness and sports performance tests, the wearable film improved 200 m sprint performance by 0.8% ± 0.4% (p = 0.039). It also maintained subjective thermal sensation during the warm-up transition phase, with no significant decline at 5 or 10 min after the warm-up and a significant decrease only at 15 min (p = 0.02), while thermal comfort remained stable, suggesting improved neuromuscular readiness. This research provided a novel strategy for the fabrication of advanced aerogel-based wearable devices aimed at precision thermal management and athletic performance optimization.

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