Abstract
The growing demand for wearable electronics and the Internet of Things (IoT) calls for flexible piezoelectric energy harvesters with substantially improved power output. Polyacrylonitrile (PAN) polymers, with their high polarization and excellent thermal stability, are among the most promising candidates for efficient flexible piezoelectric materials. However, the performance of existing PAN-based harvesters remains limited, and strategies for further enhancing their output are still insufficiently explored. Herein, this study aims to overcome the output bottleneck of PAN-based PENGs by implementing a novel mechanical excitation strategy. Using electrospun flexible PAN-BaTiO(3) nanocomposite films, we systematically compared the electromechanical responses under conventional compression and impact modes. Real-time synchronized force-current measurements in compression mode revealed that the output current increases progressively with drive frequency (2-10 Hz). Specifically, the PENG with PAN-20 wt.% BaTiO(3) achieved a peak current of 0.33 mA at 10 Hz, showing an approximately 7.9-fold enhancement over its pure PAN counterpart. More importantly, under 6 Hz impact excitation, the device exhibited a remarkable output current density of 1.0 mA cm(-2) and a peak power density of 256.5 µW cm(-2). This current density is 95 times higher than that in compression mode at a comparable frequency and surpasses the performance of most recently reported piezoelectric and triboelectric nanogenerators. With an effective area of 16 cm(2), the PENG could simultaneously illuminate up to 275 commercial LEDs or 100 individual bulbs and maintained stable operation over 63,530 cycles. This work overcomes the output bottleneck in low-frequency energy harvesting and provides an effective pathway toward practical energy-harvesting applications.