Facile Synthesis of Polypyrrole/MnO(2)/Carbon Cloth Composites for Supercapacitor Electrodes

一种简便合成聚吡咯/MnO(2)/碳布复合材料及其在超级电容器电极中的应用

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Abstract

In the development of flexible smart electronics, fabricating electrodes with optimized architectures to achieve superior electrochemical performance remains a significant challenge. This study presents a two-step synthesis and characterization of a polypyrrole (PPy)-MnO(2)/carbon cloth (CC) nanocomposite. The MnO(2)/CC substrate was first prepared via the hydrothermal method, followed by uniform PPy coating through vapor-phase polymerization in the presence of an oxidizing agent. Electrochemical measurements revealed substantial enhancement in performance, with the specific capacitance increasing from 123.1 mF/cm(2) for the MnO(2)/CC composite to 324.5 mF/cm(2) for the PPy/MnO(2)/CC composite at a current density of 2.5 mA/cm(2). This remarkable improvement can be attributed to the synergistic effects between the conductive PPy polymer and MnO(2)/CC substrate and the formation of additional ion transport channels facilitated by the PPy coating. This work provides valuable insights for designing high-performance electrode materials and advances the development of composite-based energy storage devices.

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