Tetrahedral framework nucleic acid delivery of emodin enables precision antibacterial and anti-inflammatory therapy for drug-resistant Staphylococcus aureus

四面体框架核酸递送大黄素可实现对耐药金黄色葡萄球菌的精准抗菌和抗炎治疗

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Abstract

BACKGROUND: Staphylococcus aureus skin infections represent a persistent clinical challenge owing to their high pathogenicity, multidrug resistance, and biofilm-associated recurrence, which collectively impair antibiotic penetration and exacerbate host inflammation. Emodin, a natural anthraquinone with dual antibacterial and anti-inflammatory activities, has shown therapeutic promise but suffers from poor solubility, rapid clearance, and a lack of pathogen specificity, limiting its translational potential. Here, we developed a multifunctional nanoplatform composed of tetrahedral framework nucleic acids (tFNAs), in which Emodin was noncovalently loaded onto a DNA scaffold to enable sustained release, and a Staphylococcus aureus-specific aptamer was displayed to enable targeted bacterial recognition. Notably, this aptamer-guided design is pathogen oriented, aiming for bacteria-associated enrichment in infected wounds rather than targeting host inflammatory markers or specific immune cell subsets. RESULTS: This system markedly potentiated the antibacterial efficacy of Emodin against methicillin-resistant S. aureus (MRSA), significantly inhibited biofilm formation, and disrupted mature biofilms. In murine infection models, the Apt-tFNAs-Emo reduced the bacterial burden, alleviated oxidative stress and TLR4/NF-κB activation, suppressed proinflammatory cytokine production, and accelerated wound healing by restoring collagen deposition and epidermal architecture. CONCLUSIONS: Overall, this study establishes an aptamer-targeted nucleic acid nanoplatform that integrates antimicrobial delivery, biofilm disruption, and host immunomodulation, offering a promising therapeutic strategy for multidrug-resistant S. aureus skin infections.

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