Crystal structure and Hirshfeld surface studies of 4-bromo-2-chloro-phenyl (2E)-3-[4-(pent-yloxy)phen-yl]prop-2-enoate

4-溴-2-氯苯基(2E)-3-[4-(戊氧基)苯基]丙-2-烯酸酯的晶体结构和Hirshfeld表面研究

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Abstract

The asymmetric unit of the compound C(20)H(20)BrClO(3) contains one independent mol-ecule in which the aromatic rings are oriented at a dihedral angle of 83.30 (2)°. An intra-molecular C-H⋯O contact generates a five-membered S(5) ring motif. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules through R (1) (2)(6), R (2) (2)(10), R (2) (2)(14) hydrogen-bond motifs. The structure is consolidated by C-H⋯π inter-actions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H⋯H (32.8%), C⋯H/H⋯C (28.1%), O⋯H/H⋯O (14.0%) Br⋯H/H⋯Br (12.5%) and Cl⋯H/H⋯Cl (10.6%) inter-actions.

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