A case for resonant X-ray Bragg diffraction by a collinear antiferromagnet Li(2)Ni(3)P(4)O(14)

共线反铁磁体 Li(2)Ni(3)P(4)O(14) 的共振 X 射线布拉格衍射案例

阅读:4

Abstract

Magnetic axial and polar (Dirac) nickel multipoles contribute to resonant X-ray Bragg amplitudes in a symmetry-informed analysis of monoclinic Li(2)Ni(3)P(4)O(14) presented for future diffraction experiments. Magnetic long-range order below a temperature of ≃ 14.5 K can be viewed as a two-dimensional trimerized antiferromagnet with Ni ions in two Wyckoff positions in the centrosymmetric (1) magnetic space group P2(1)/c. It permits the coupling to circular polarization in the primary X-ray beam, unlike the corresponding diffraction by an antiferromagnet characterized by anti-inversion (1') and a linear magnetoelectric effect, e.g. historically significant chromium sesquioxide (Cr(2)O(3)) and Cu(2)(MoO(4))(SeO(3)) [Lovesey & van der Laan (2024). Phys. Rev. B 110, 174442]. The space group is inferred from neutron Bragg diffraction patterns, without an allowance for permitted Dirac dipoles (anapoles) and quadrupoles [Chikara et al. (2025). Phys. Rev. B 112, 014438].

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。