Abstract
This study centers around examining the impact of introducing varying (small) quantities of crude oil into mineral oil (Exxsol D60) on the resultant properties of dispersions and emulsions in oil-salty-water mixture properties such as rheology, droplet size distribution, separation duration, and interfacial tension. The experimentation encompassed bottle tests and a compact flow loop configuration featuring a 2 m horizontal pipe segment. The findings indicate that blends of oil infused with crude oil, combined with salty water at water ratios of 25% and 50%, necessitate an extended duration for separation and for the establishment and stabilization of interfaces, in contrast to mixtures of unaltered oil and saline water. To illustrate, in samples with spiking concentrations ranging from 200 to 800 ppm within a 25% water fraction, the separation period escalates from 51 s to 2 min and 21 s. Interestingly, when the water fraction increased to 75 percent, the impact of crude oil spiking on separation time was minimal. The analysis revealed that the Pal and Rhodes emulsion viscosity model yielded the most accurate predictions for the viscosity of resulting emulsions. The introduction of crude oil spiking elevated emulsion viscosity while diminishing interfacial tension from 30.8 to 27.6 mN/m (800 ppm spiking). Lastly, a comparative assessment was performed between droplet size distributions in the devised dispersed pipe flow and observed in an actual emulsion system comprising crude and salty water.