Abstract
The photo-reduction of bromate (BrO3 -) has attracted much attention due to the carcinogenesis and genotoxicity of BrO3 - in drinking water. In this study, a heterojunction photocatalyst was developed by depositing Au nanoparticles (NPs) onto P25 TiO2 NPs through a one-pot, solvent-thermal process. Due to the unique properties of Au, the Au NPs deposited on the TiO2 surface created a Schottky barrier between the metal and the semiconductor, leading to an effective separation of photo-generated charge carriers as the Au nanoparticles served as electron sinks. The Au/TiO2 photocatalyst demonstrated efficient reduction of BrO3 - under UV light illumination without the need for sacrificial agents. The effect of different Au loading of Au/TiO2 was systematically investigated for its influence on the generation of electrons and the reduction ability of BrO3 -. The results indicate that the 1% Au/TiO2 catalyst exhibited a higher concentration of localized electrons, rendering it more effective in BrO3 - removal. The photocatalytic efficiency for BrO3 - reduction decreased upon the addition of K2S2O8 as an electron quencher, suggesting that the primary factor in this photo-reduction process was the availability of electrons. These findings hold promise for the potential application of the Au/TiO2 catalyst in the removal of BrO3 - from drinking water through photo-reduction.