Hard-template-engaged formation of Co(2)V(2)O(7) hollow prisms for lithium ion batteries

利用硬模板法制备Co₂V₂O₇空心棱柱用于锂离子电池

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Abstract

Highly uniform and monodispersed Co(2)V(2)O(7) hollow nanoprisms are successfully fabricated via a simple hard-template-engaged strategy. In such synthesis, Co acetate hydroxide plays the important role of not only the cobalt source, but also the sacrificial template. After coating with a carbon layer, the as-obtained Co(2)V(2)O(7) hollow nanoprisms exhibit apparently enhanced lithium-ion-battery performances. It has shown a high specific capacity of around 946 mA h g(-1) at a current density of 100 mA g(-1), excellent cycling stability up to 300 cycles at a current density of 1 A g(-1), and superior rate performance, which is much better than carbon coated solid Co(2)V(2)O(7) samples.

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