Abstract
Eu(2+) and Eu(3+) doubly doped ZnWO₄ nanoplates with highly exposed {100} facets were synthesized via a facile hydrothermal route in the presence of surfactant cetyltrimethyl ammonium bromide. These ZnWO₄ nanoplates were characterized using scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectrometry, diffuse UV-vis reflectance spectroscopy, photoluminescence spectrophotometry, and photoluminescence lifetime spectroscopy to determine their morphological, structural, chemical, and optical characteristics. It is found that Eu-doped ZnWO₄ nanoplates exhibit superior photo-oxidative capability to completely mineralize the methyl orange into CO₂ and H₂O, whereas undoped ZnWO₄ nanoparticles can only cleave the organic molecules into fragments. The superior photocatalytic performance of Eu-doped ZnWO₄ nanoplates can be attributed to the cooperative effects of crystal facet engineering and defect engineering. This is a valuable report on crystal facet engineering in combination with defect engineering for the development of highly efficient photocatalysts.