Abstract
Cationic porous organic polymers have a unique advantage in removing radioactive iodine from the aqueous phase because iodine molecules exist mainly in the form of iodine-containing anions. However, halogen anions will inevitably be released into water during the ion-exchange process. Herein, we reported a novel and easy-to-construct zwitterionic hypercrosslinked polymer (7AIn-PiP)-containing cationic pyridinium-type group, uncharged pyridine-type group, pyrrole-type group, and even an electron-rich phenyl group, which in synergy effectively removed 94.2% (456 nm) of I(2) from saturated I(2) aqueous solution within 30 min, surpassing many reported iodine adsorbents. Moreover, an I(2) adsorption efficiency of ~95% can still be achieved after three cyclic evaluations, indicating a good recycling performance. More importantly, a unique dual 1,3-dipole was obtained and characterized by (1)H/(13)C NMR, HRMS, and FTIR, correlating with the structure of 7AIn-PiP. In addition, the analysis of adsorption kinetics and the characterization of I(2)@7AIn-PiP indicate that the multiple binding sites simultaneously contribute to the high affinity towards iodine species by both physisorption and chemisorption. Furthermore, an interesting phenomenon of inducing the formation of HIO(2) in unsaturated I(2) aqueous solution was discovered and explained. Overall, this work is of great significance for both material and radiation protection science.