A Study on Hollow Mesoporous Silica Nanoparticles with Long-Term Cycling

空心介孔二氧化硅纳米粒子的长期循环性能研究

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Abstract

As electronic technologies continue to advance, the demand for high-performance and safe batteries has steadily increased. However, silicon-based anode materials experience severe volume expansion and poor structural stability during cycling, which limits their practical application. In this study, we synthesized hollow mesoporous silica to develop an anode material with long-term cycling stability. Electrochemical analysis revealed that the material exhibited low-capacity decay, decreasing from 125 mA·h·g(-1) to 120 mA·h·g(-1) at a C-rate of 20 C, and retained a 49 mA·h·g(-1) after 500 charge-discharge cycles at a C-rate of 10 C. Furthermore, electrochemical impedance spectroscopy and Scanning Electron Microscopy analysis confirmed that the hollow mesoporous silica structure is long-term cycling stability in the anode.

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