A Metallo Pro-Drug to Target Cu(II) in the Context of Alzheimer's Disease

一种靶向Cu(II)的金属前药在阿尔茨海默病中的应用

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Abstract

Alzheimer's disease and oxidative stress are connected. In the present communication, we report the use of a Mn(II) -based superoxide dismutase (SOD) mimic ([Mn(II) (L)](+) , 1(+) ) as a pro-drug candidate to target Cu(II) -associated events, namely, Cu(II) -induced formation of reactive oxygen species (ROS) and modulation of the amyloid-β (Aβ) peptide aggregation. Complex 1(+) is able to remove Cu(II) from Aβ, stop ROS and prevent alteration of Aβ aggregation as would do the corresponding free ligand LH. Using 1(+) instead of LH in further biological applications would have the double advantage to avoid the cell toxicity of LH and to benefit from its proved SOD-like activity.

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