Optimized NiCo(2)O(4)/rGO hybrid nanostructures on carbon fiber as an electrode for asymmetric supercapacitors

优化后的NiCo(2)O(4)/rGO复合纳米结构在碳纤维上作为非对称超级电容器电极

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Abstract

The NiCo(2)O(4) nanowires and reduced graphene oxide (rGO) hybrid nanostructure has been constructed on carbon fibers (NiCo(2)O(4)/rGO/CF) via a hydrothermal method. The effects of graphene oxide (GO) concentration on the structure and performance of the NiCo(2)O(4)/rGO/CF were investigated in detail to obtain the optimized electrode. When the GO concentration was 0.4 mg ml(-1), the rGO/NiCo(2)O(4)/CF composite exhibited a maximum specific capacitance of 931.7 F g(-1) at 1 A g(-1), while that of NiCo(2)O(4)/CF was 704.9 F g(-1). Furthermore, the NiCo(2)O(4)/rGO/CF//AC asymmetric supercapacitor with a maximum specific capacitance of 61.2 F g(-1) at 1 A g(-1) was fabricated, which delivered a maximum energy density (24.6 W h kg(-1)) and a maximum power density (8477.7 W kg(-1)). Results suggested that the NiCo(2)O(4)/rGO/CF composite would be a desirable electrode for flexible supercapacitors.

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