Abstract
The maximum temperature limit at which liquid boils explosively is referred to as the superheat limit of liquid. Through various experimental studies on the superheating limit of liquids, rapid evaporation of liquids has been observed at the superheating limit. This study explored the water nucleation process at the superheat limit achieved in micro-platinum wires using a molecular interaction model. According to the molecular interaction model, the nucleation rate and time delay at 576.2 K are approximately 2.1 × 10(11)/(μm(3)μs) and 5.7 ns, respectively. With an evaporation rate (116.0 m/s) much faster than that of hydrocarbons (14.0 m/s), these readings show that explosive boiling or rapid phase transition from liquid to vapor can occur at the superheat limit of water. Subsequent bubble growth after bubble nucleation was also considered.