Preparation of gypsum with high purity and whiteness from phosphogypsum for CO(2) mineral sequestration

利用磷石膏制备高纯度、高白度石膏用于二氧化碳矿物封存

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Abstract

Phosphogypsum (PG) is a solid waste product generated during wet-process phosphoric acid production. Various impurities considerably reduce the purity, whiteness, and application range of PG. This article analyzes the physical properties of PG in detail and systematically examines the content and distribution of impurities. Based on the obtained results, a simple process for the efficient removal of almost all impurities in the PG is proposed. The purity and whiteness of the purified gypsum (CaSO(4)) significantly increased to 99% and 92%, respectively. The migration of impurities and the material balance of this process were then analyzed. Most importantly, the purified gypsum showed high CO(2) sequestration efficiency for CO(2) mineral sequestration, through which a high value-added CaCO(3) product was obtained.

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