Synthesis and photocatalytic properties of visible-light-responsive, three-dimensional, flower-like La-TiO(2)/g-C(3)N(4) heterojunction composites

可见光响应型三维花状La-TiO(2)/gC(3)N(4)异质结复合材料的合成及光催化性能

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Abstract

We prepared a new three-dimensional, flower-like La-TiO(2)/g-C(3)N(4) (LaTiCN) heterojunction photocatalyst using a solvothermal method. Analysis and characterization were performed by conducting scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform-infrared spectroscopy, ultraviolet-visible spectrophotometry, and nitrogen adsorption and desorption. The prepared g-C(3)N(4) nanosheets could reach 100 nm in size and covered the TiO(2) surface. A tightly bound interface formed between the g-C(3)N(4) and TiO(2), speeding up the effective transfer of photo-induced electrons. In addition, the incorporation of La(3+) reduced the electron-hole recombination efficiency. Consequently, the prepared La-TiO(2)/g-C(3)N(4) composite material exhibited better visible-light catalytic activity than pure TiO(2).

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