Abstract
Since the invention of the triboelectric nanogenerator (TENG), porous polymer materials (PPMs), with different geometries and topologies, have been utilized to enhance the output performance and expand the functionality of TENGs. In this review, the basic characteristics and preparation methods of various PPMs are introduced, along with their applications in TENGs on the basis of their roles as electrodes, triboelectric surfaces, and structural materials. According to the pore size and dimensionality, various types of TENGs that are built with hydrogels, aerogels, foams, and fibrous media are classified and their advantages and disadvantages are analyzed. To deepen the understanding of the future development trend, their intelligent and multifunctional applications in human-machine interfaces, smart wearable devices, and self-powering sensors are introduced. Finally, the future directions and challenges of PPMs in TENGs are explored to provide possible guidance on PPMs in various TENG-based intelligent devices and systems.