Synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phen-yl]acrylo-nitrile

新型芘基化合物3,3-二苯基-2-[4-(芘-1-基)苯基]丙烯腈的合成、晶体结构和聚集诱导发光

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Abstract

The title organic compound, C(37)H(23)N, crystallizing in the triclinic space group P [Formula: see text], has been designed, synthesized and characterized by single-crystal X-ray diffaction, MS, NMR and elemental analysis. There are alternating relatively strong and weak intermolecular π-π interactions between adjacent pyrene ring systems, forming a one-dimensional supramolecular structure. The compound is weakly fluorescent in THF solution, but it is highly emissive in the condensed phase, revealing distinct aggregation-induced emission (AIE) characteristics.

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