Crystal structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κO-meth-yl)amino-κN]eth-yl}(carboxyl-ato-κO-meth-yl)amino-κN)eth-yl](carb-oxy-meth-yl)aza-niumyl}acetato)-gallium(III) trihydrate

水合物-(2-{[2-({2-[双-(羧基-κO-甲基)氨基-κN]乙基}(羧基-κO-甲基)氨基-κN)乙基](羧基-甲基)氮杂鎓基}乙酸根)-三水合镓(III)的晶体结构

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Abstract

In the title Ga(III) complex compound with pentetic acid, [Ga(C(14)H(20)N(3)O(10))(H(2)O)]·3H(2)O, the Ga(III) centre is bound in a slightly distorted octa-hedral coordination sphere by two amine N atoms, three carboxyl-ate O atoms and one water O atom. The complex mol-ecule exists as a zwitterion. In the crystal, the complexes are linked to each other via O-H⋯O and C-H⋯O hydrogen bonds, forming layers parallel to (001). Three uncoordinating water mol-ecules link the complex layers via O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional network.

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