Abstract
Dynamic hydrogels have attracted considerable attention in the application of flexible electronics, as they possess injectable and self-healing abilities. However, it is still a challenge to combine high conductivity and antibacterial properties into dynamic hydrogels. In this work, we fabricated a type of dynamic hydrogel based on acylhydrazone bonds between thermo-responsive copolymer and silver nanoparticles (AgNPs) functionalized with hydrazide groups. The hybrid hydrogels exhibited sol-gel transition, self-healable, injectable and thermo-responsive abilities. The self-healing efficiency was over 92%. Moreover, the hydrogel displayed antimicrobial properties and high conductivity (6.85 S/m). Notably, the fabricated hydrogel-based sensors exhibited strain and temperature sensing (22.05%/°C) and could detect human motion and speech, and electrocardiographic (ECG) and electromyography (EMG) signals. Overall, this work provides a simple strategy to synthesize AgNPs-based dynamic hydrogels with multi-functions, and the hydrogels may find potential applications in antibacterial wearable electronics, health monitoring and speech recognition.