Enhanced Photoluminescence of R6G Dyes from Metal Decorated Silicon Nanowires Fabricated through Metal Assisted Chemical Etching

通过金属辅助化学蚀刻制备的金属装饰硅纳米线中 R6G 染料的光致发光增强

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作者:Ioannis Kochylas, Anastasios Dimitriou, Maria-Athina Apostolaki, Maria-Christina Skoulikidou, Vlassios Likodimos, Spiros Gardelis, Nikolaos Papanikolaou

Abstract

In this study, we developed active substrates consisting of Ag-decorated silicon nanowires on a Si substrate using a single-step Metal Assisted Chemical Etching (MACE) process, and evaluated their performance in the identification of low concentrations of Rhodamine 6G using surface-enhanced photoluminescence spectroscopy. Different structures with Ag-aggregates as well as Ag-dendrites were fabricated and studied depending on the etching parameters. Moreover, the addition of Au nanoparticles by simple drop-casting on the MACE-treated surfaces can enhance the photoluminescence significantly, and the structures have shown a Limit of Detection of Rhodamine 6G down to 10-12 M for the case of the Ag-dendrites enriched with Au nanoparticles.

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