Effect of Graphene on the Mechanical Properties of Recycled High-Density and High-Molecular-Weight Polyethylene Blends

石墨烯对再生高密度高分子量聚乙烯共混物力学性能的影响

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Abstract

This study uses an extrusion process to formulate blends based on recycled high-density and high-molecular-weight polyethylene (recHDPE, recHMWPE) for the manufacture of rainwater drainage pipes. The main objective of this project is to investigate the effects of incorporating graphene on the mechanical, thermal, and stress-cracking resistance properties of the recycled HDPE and HMWPE blends. Also, it aims to demonstrate that the addition of graphene may enable the use of different recycled polymers without compromising their properties. The effects of adding two amounts of graphene (0.5 and 1%) to recycled blends on the tensile and flexion properties, stress crack resistance (SCR) (using a notched crack ligament stress (NCLS) test), thermal behavior (using a differential scanning calorimeter (DSC) and a rheological plastometer) were investigated. The experimental results showed a significative enhancement when adding graphene in the SCR, some tensile properties (elongation at break and tensile strength), and flexural modulus. However, physical characterization showed that the samples containing 0.5% graphene exhibited lower crystallinity compared to the reference and, for the blend with 1% graphene, the fluidity also decreased for the blend filled with the graphene compared to the reference blend without any filler.

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