Abstract
Perovskite solar cells (PSCs) have attracted significant attention in recent years owing to some of their advantages: high-efficiency, low cost and ease of fabrication. In perovskite photovoltaic devices, charge transport layers play a vital role for selectively extracting and transporting photo-generated electrons and holes to opposite electrodes. Therefore, it is very important to prepare high-quality charge transport layers using simple processes at low cost. As reported, In2S-based electron selective layers display excellent performance including high solar-cell efficiency and negligible hysteresis. In this study, a simple chemical method was developed to prepare In2S3 thin films as the electron selective layers in organic-inorganic hybrid perovskite photovoltaic devices to shorten the fabrication time and simplify the technology, which can provide a new avenue for a low-cost and solution-processed method. By optimizing the preparation conditions, it was demonstrated that In2S3 thin film prepared using our straightforward chemical approach have higher electron extraction efficiency and comparable efficiency compared with archetypical TiO2 as the electron transport layer (ETL) in perovskite photovoltaic device.