Mechanical Properties of Ti(3)AlC(2)/Cu Composites Reinforced by MAX Phase Chemical Copper Plating

MAX相化学镀铜增强Ti(3)AlC(2)/Cu复合材料的力学性能

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Abstract

Among the various reinforcement phases available in Cu-based composites, the unique layered structure and easy diffusion of A-layer atoms make MAX phases more suitable for reinforcing a copper matrix than others. In this study, Cu-coated Ti(3)AlC(2) particles (Cu@Ti(3)AlC(2)) were prepared through electroless plating, and Cu@Ti(3)AlC(2)/Cu composites were fabricated via vacuum hot-press sintering. The phase composition and microstructure of both Cu@Ti(3)AlC(2) powder and composites were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results demonstrate the creation of successful electroless copper plating to obtain a Cu coating on Ti(3)AlC(2) particles. At 850 °C, a small amount of Ti(3)AlC(2) particles decompose to form TiCx, while Al atoms from the A layer of MAX phase diffuse into the Cu matrix to form a solid solution with Cu(Al). The test results reveal that the density of the Cu@Ti(3)AlC(2)/Cu composite reaches 98.5%, with a maximum compressive strength of 705 MPa, which is 8.29% higher than that of the Ti(3)AlC(2)/Cu composite. Additionally, the compressive strain reaches 37.6%, representing an increase of 12.24% compared to that exhibited by the Ti(3)AlC(2)/Cu composite.

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