Reduction in Heavy Rare Earth Diffusion Sources in Sintered Nd-Fe-B Magnets via Grain Boundary Diffusion of Dy(70)Ce(70-x)Cu(30)

通过 Dy(70)Ce(70-x)Cu(30) 晶界扩散减少烧结 Nd-Fe-B 磁体中的重稀土扩散源

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Abstract

This study investigates the effect of Ce on the diffusion behavior of Dy-Cu alloys. The addition of Ce reduces the diffusion source melting point and promotes the formation of low-melting alloy phases, benefiting the diffusion behavior. The diffusion source with 10 wt.% of Ce shows the best magnetic performance, the coercivity of the magnet increases from 18.47 kOe to 23.60 kOe, and the incremental coercivity reaches 5.13 kOe. Ce diffusion improves the utilization of Dy, enhances diffusion uniformity, and promotes coercivity improvement. Ce also optimizes and regulates grain boundary phase structure distribution, consistent with magnetic property changes. Dy(70)Cu(30) with an excessive thick shell layer wastes Dy and reduces utilization, while Dy(60)Ce(10)Cu(30) has a relatively thin and uniform shell layer. Ce mainly distributes in the intergranular phase region, promoting Dy diffusion from the intergranular phase to form a shell layer. Excessive Ce can distort the magnet's crystal structure, hindering magnetic property improvement. This study provides insights into optimizing the diffusion process and improving the Dy-Cu alloy.

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