Abstract
This study examined the impact of acid hydrolysis, tempo oxidation, and mechanical grinding on the physical, thermal, and structural properties of α-chitin nanocrystals and nanofibers. The manufacturing methods could influence the diameter, functional groups, and crystal patterns of the resulting nanoparticles. Analysis of the DLS results revealed that the size of acidic nanocrystals were smaller and showed improved dispersibility. The XRD patterns indicated that the chemical and mechanical treatments did not alter the crystalline arrangement of the α-chitin. FT-IR spectra analysis revealed that the chemical and mechanical methods did not affect the functional groups of the nanoparticles. DSC results showed that the nanoparticles had good thermal stability up to 400 °C, and it was found that the nanofibers had better thermal resistance due to their longer length. In the FE-SEM images, the nanoparticles were observed as fiber mats with a length of more than 100 nm. It was also found that the diameter of the nanoparticles was less than 100 nm.