Study on Gas Sorption and Iodine Uptake of a Metal-Organic Framework Based on Curcumin

基于姜黄素的金属有机框架对气体吸附和碘吸收的研究

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Abstract

Medi-MOF-1 is a highly porous Metal-Organic framework (MOF) constructed from Zn(II) and curcumin. The obtained crystal was characterized using powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM). A micrometer-sized crystal with similar morphology was successfully obtained using the solvothermal method. Thanks to its high surface area, good stability, and abound pores, the as-synthesized medi-MOF-1 could be used as a functional porous material to adsorb different gases (H(2), CO(2), CH(4), and N(2)) and iodine (I(2)). The activated sample exhibited a high I(2) adsorption ability of 1.936 g g(-1) at room temperature via vapor diffusion. Meanwhile, the adsorbed I(2) could be released slowly in ethanol, confirming the potential application for I(2) adsorption.

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