Abstract
Increasing the recovery in electrodialysis desalination may be achieved using a single-pass operation at different linear flow velocity values in the diluate and concentrate compartments. The risk of inner leakage as well as membrane bulging and damage can be minimized by controlling the pressure difference between the diluate and concentrate compartments. This solution has been tested in a pilot plant for initial demineralization of river water using an electrodialyzer of our own design. Both under- and overlimiting regimes have been tested, as well as long work cycles between electrode polarity reversals. Water with a conductivity of about 500 µS/cm was desalinated at a recovery of 70-75%, and the desalination degree was 75-96%. It was also found that the unit cost could be decreased by 52% compared to a commercial solution when the diluate conductivity was 74.3 μS/cm. A deep demineralization, from 511 μS/cm down to 17.9 μS/cm in a single-stage EDR or 8.52 μS/cm in a two-stage EDR, was also confirmed experimentally at the pilot scale.