Low-salinity water flooding by a novel hybrid of nano γ-Al(2)O(3)/SiO(2) modified with a green surfactant for enhanced oil recovery

一种新型纳米γ-Al₂O₃/SiO₂复合材料经绿色表面活性剂改性后,用于低盐度水驱油以提高采收率

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Abstract

This paper introduces a hybrid enhanced oil recovery (HEOR) method that combines a low-salinity water flooding (LSWF) and nanoparticles (NPs) stabilized with a green surfactant. We experimentally investigated the use of combinations of silica (SiO(2)) and gamma alumina (γ-Al(2)O(3)) nanohybrids stabilized with Gum Arabic (GA) at different water salinities. Nanofluids (NFs) were prepared by dispersing γ-Al(2)O(3) and SiO(2) NPs (0.1 wt%) in deionized water (DW), synthetic seawater (SSW), 2, 5, and 10 times diluted samples of synthetic seawater (in short 2-DSSW, 5-DSSW and 10-DSSW, respectively). The challenge is that NPs become unstable in the presence of cations in saline water. Moreover, an attempt was made to introduce NFs with high stability for a long period of time as the optimal NFs. The effects of temperature on the behaviour of optimal NFs in the presence of different base fluids, distinct mass ratios of γ-Al(2)O(3)/SiO(2) and various concentrations of surfactant were analysed via interfacial tension (IFT) and viscosity measurements. The results of the viscosity measurement showed that with increasing temperature, the NPs dispersed in DW had lower viscosity than NPs dispersed in various salinities. However, the IFT measurement for NPs dispersed in different base-fluids revealed that with increasing temperature and presence of cations in saline water, IFT values decreases. Although, the minimum IFT for hybrid nanofluid (HNF) γ-Al(2)O(3)/SiO(2) modified with GA and dispersed in 10-DSSW was reported 0.99 mN/m. Finally, according to the micromodel flooding results, in oil-wet conditions, the highest oil recovery for combination γ-Al(2)O(3)/SiO(2) modified with GA and dispersed in 2-DSSW was reported 60.34%. It was concluded that NFs modified with GA could enhanced applicability of LSWF via delay in breakthrough time and improving sweep efficiency.

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