Abstract
Historical chemical production sites often harbor irregularly distributed solid waste landfills, posing significant environmental risks. Traditional drilling methods, while accurate, are inefficient for comprehensive characterization due to high costs and spatial limitations. This study aims to develop an integrated geophysical drilling approach to accurately delineate the spatial distribution and volume of landfilled solid waste (predominantly organic pollutants) at two decommissioned chemical plant sites (total area: 8954 m(2)). Methods: We combined (1) geophysical surveys (transient electromagnetic (TEM, 50 profiles, 2936 points), high-density resistivity (HDR, 2 profiles, 192 points), and ground-penetrating radar (GPR, 22 profiles, 1072.1 m)) and (2) systematic drilling verification (136 boreholes, ≤10 m × 10 m density). Anomalies were interpreted through integrating geophysical responses, historical records, and borehole validation. Spatial modeling was conducted using Kriging interpolation in EVS software. The results show that (1) the anomalies exhibited a "sparse multi-point distribution" across zones A2 (primary waste concentration), A4, and A6, which were differentiated into solid waste, foundations, contaminated soil, voids, and cracks; (2) drilling confirmed solid waste at nine locations (A2: "multi-point, small-quantity" residues; A6: contaminated clay layers with garbage) with irregular thicknesses (0.2-1.3 m); (3) TEM identified diagnostic medium-high-resistivity anomalies (e.g., 28-37 m in A4L3), while GPR detected 17 shallow anomalies (only one validated as waste); and (4) the total waste volume was quantified as 266.9 m(3). The methodology reduced the field effort by ∼35% versus drilling-only approaches, resolved geophysical limitations (e.g., HDR's volume effect overestimating the thickness), and provided a validated framework for efficient characterization of complex historical landfills.