Abstract
This study introduces an innovative process for stabilizing BOF slag by blowing oxygen into molten slag, addressing challenges associated with conventional methods that require silica injection. Molten BOF slag from a steelmaking workshop at China Steel Corporation is directly modified at the slag modification station, where chemical compositions and crystalline phases are analyzed under varying oxygen injection amounts. In 70 industrial trials (20-25 tons per trial) with the basicity of the BOF slag ranging from 2.2 to 4.5, the reduction in the slag expansion rate increases proportionally with oxygen-blowing amounts. Oxygen blowing facilitates the oxidation of FeO to Fe(2)O(3), which reacts with f-CaO to form volumetrically stable C(2)AF (brownmillerite, Ca(2)Al(x)Fe(2-x)O(5)), as confirmed by XRD and SEM-EDX analyses. The treated BOF slag exhibits excellent volumetric stability (expansion < 0.5%), lower pH (10.6-10.8) in comparison to original BOF slag, and compliance with Taiwan's EPA-leaching regulations. This stabilized slag demonstrates potential for engineering applications, such as pavement bricks, concrete products, and high-value engineered stones. Additionally, the high brownmillerite content highlights its promise for low-carbon cement applications, offering a scalable and cost-effective solution for BOF slag utilization in the steel industry.