Enhancement of Fracture Toughness of Inner Liner Material for Type IV Hydrogen Storage Cylinders Based on Molecular Dynamics Method

基于分子动力学方法的IV型储氢钢瓶内衬材料断裂韧性增强

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Abstract

To develop liner materials with improved toughness, this study combines molecular dynamics simulations and experimental testing to investigate the effect of different mass ratios (10/0, 7/3, 6/4, 4/6, 3/7, and 0/10) of high-density polyethylene (HDPE)/polyamide 6 (PA6) on their fracture toughness of the composites. The fracture toughness was quantitatively assessed using the J-integral method, while the material's behavior in terms of crack propagation during tensile deformation was examined at the molecular level. The results reveal that as the HDPE mass ratio increases, the fracture toughness of the composites also gradually improves. Furthermore, the fracture toughness of four materials (PA6, 4HDPE/6PA6, 7HDPE/3PA6, and HDPE) was tested using the essential work of the fracture method. The trend observed in the simulation results was in agreement with the experimental results, validating the reliability of the molecular dynamics simulation.

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