Abstract
Efficient artificial light-harvesting systems (ALH) involving energy transfer via FRET in an aqueous environment has been reported. Hydrazone ligands L1-L3 and -BF(2) complexes (BODIHYs; B1-B3) derived from these have been synthesized and meticulously characterized by various techniques like(1)H, (13)C, (11)B, (19)F NMR, ESI-MS, UV-vis, fluorescence spectroscopy, and structures of B1 and B2 unequivocally determined by X-ray single crystal analyses. Applicability of the B1-B3 have been examined as a LHS platform and categorically shown that these in combination with rhodamine B (RhB) display efficient light harvesting activity under aqueous conditions via aggregation-induced emission (AIE). Calculated energy transfer efficiency and antenna effect for the BODIHYs are significantly high (B1 = 22%, 5.04; B2 = 18%, 4.07) at a donor/acceptor ratio of 23:1. Furthermore, hypsochromic shift shown by B1 and B2 after grinding completely reverses upon exposure to dichloromethane vapors. Powder X-ray diffraction (PXRD) analyses before and after grinding revealed that the external forces modify crystal packing by disrupting weak intra- and intermolecular interactions within the molecules.