Ecotoxicity Study of New Composite Materials Based on Epoxy Matrix DER-331 Filled with Biocides Used for Industrial Applications

工业用环氧基质 DER-331 填充杀菌剂的新型复合材料的生态毒性研究

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作者:Anton Panda, Kostiantyn Dyadyura, Jan Valíček, Marta Harničárová, Milena Kušnerová, Tatyana Ivakhniuk, Liudmyla Hrebenyk, Oleksandr Sapronov, Vitalii Sotsenko, Pavlo Vorobiov, Vitalii Levytskyi, Andriy Buketov, Iveta Pandová

Abstract

The impact of fillers in the epoxy oligomer on the test culture of the marine ecosystem was investigated. The content of additive-biocides-was selected based on the complex research using STAT-GRAPHICS® Centurion XVI. The ecotoxicity of composite surfaces was determined in model systems using methods which are standard in eco-microbiology. The microorganism was identified by studying morphological, cultural, biochemical, and antigenic properties. Studies of the structure and the microrelief of the surfaces of composite materials were conducted using scanning electron microscopy (SEM) and X-ray energy dispersive spectroscopy. Based on comprehensive research, it was established that the composition of oxytetracycline with content of q = 1.5 wt% and nanosilver with a content of q = 0.075 wt% per 100 wt% of the DER-331 oligomer and 10 parts by the mass of the TETA hardener ensures the formation of a porous nano-heterogeneous structure of the coating, which leads to the acceleration of the release of silver ions from the surface of the polymer. The rational content of the complex additives of biocides ensures adhesion to the cell wall of bacteria with subsequent penetration into it and subsequent change to the cell membrane, its death, and, therefore, the suppression of the fouling process of metal structures.

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