A facile and general approach for the direct fabrication of N-rGO-metal(metal oxides)-Pt composites as electrocatalyst for oxygen reduction reactions

一种简便、通用的直接制备 N-rGO-金属(金属氧化物)-Pt 复合材料作为氧还原反应电催化剂的方法

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作者:Xiaohong Chen, Zhaoyang Ning, Zongshang Zhou, Xundao Liu, Jianlong Lei, Supeng Pei, Yongming Zhang

Abstract

Nitrogen-doped reduced graphene oxide-metal(metal oxides) nanoparticle (N-rGO-M(MO) NPs, M = Fe, MO: M = Co, Mn) composites were prepared through a facile and general method at high temperature (800 °C). M(MO) were well-dispersed and tightly anchored on graphene sheets, which were doped with nitrogen simultaneously and further loaded with Pt nanoparticles. Those results showed a more positive onset potential, higher cathodic density, and higher electron transfer number for the ORR in alkaline media. Furthermore, N-rGO-metal(metal oxides)-Pt (N-rGO-M(MO)-Pt) nanoparticles show better durability than the commercial Pt/C catalyst, and can be used as promising potential materials in practical applications.

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