Facile synthesis of Tb-decorated graphene oxide: electrochemical stability, hydrogen storage, and corrosion inhibition of Mg AZ13 alloy in 3.5% NaCl medium

Tb修饰氧化石墨烯的简便合成:电化学稳定性、储氢性能及在3.5% NaCl介质中对Mg AZ13合金的腐蚀抑制作用

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作者:Palaniappan Nagarajan, Ivan S Cole, Aleksey Kuznetsov, Sivakumar Manickam

Abstract

Magnesium alloys have been broadly used due to their lightweight and high ductility. However, they are subject to corrosion which deteriorates their properties. To develop a novel corrosion inhibitor coating for Mg alloys, we performed functionalization of a graphene oxide (GO) matrix with Tb(iii) to improve the electrochemical behaviour and coating stability of a GO and Tb composite on the metal alloys in corrosive medium. The functionalized terbium GO material was characterized by microscopy, spectroscopy, and XRD techniques to confirm the non-covalent interactions on the active surface of the host material. The corrosion inhibition was found to be ca. 80% and electrochemical stability was observed to be high at a voltage of 900 mV. Computational studies also support the potential anti-corrosion applications of this material.

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