Dithiocarbamate-modified cellulose-based sorbents with high storage stability for selective removal of arsenite and hazardous heavy metals

具有高储存稳定性的二硫代氨基甲酸盐改性纤维素基吸附剂,用于选择性去除亚砷酸盐和有害重金属

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作者:Futo Morita, Keisuke Nakakubo, Koki Yunoshita, Masaru Endo, Foni B Biswas, Tatsuya Nishimura, Asami S Mashio, Hiroshi Hasegawa, Tsuyoshi Taniguchi, Katsuhiro Maeda

Abstract

A series of cellulose derivatives bearing dialkyl dithiocarbamate (DTC) groups were synthesized. Their ability of sorption of arsenite (As(iii)) and heavy metals and their storage stability in the solid state were investigated. Among them, DTC-modified cellulose derived from l-proline showed the highest sorption capacity for As(iii) and heavy metals to selectively remove them from aqueous media. It also showed exellent storage stability in air at 40 °C.

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