Abstract
Effective visible-light-driven Ag3PO4/GO/NiFe2O4 Z-scheme magnetic composites were successfully fabricated by a simple ion-exchange deposition method. The Ag3PO4/GO/NiFe2O4 (8%) composite exhibited excellent photocatalytic activity (degradation efficiency was ∼96% within 15 min and kinetic constant reached 0.1956 min-1) and stability when compared to Ag3PO4, NiFe2O4, and Ag3PO4/NiFe2O4 for rhodamine B (RhB) degradation. Furthermore, by electrochemical and fluorescence measurements, the Ag3PO4/GO/NiFe2O4 (8%) material also showed larger transient photocurrent, lower impedance, and longer fluorescence lifetime (7.82 ns). Comparing the activity result dependence with characterization results, it was indicated that photocatalytic activity depended on fast charge transfer from Ag3PO4 to NiFe2O4 through GO sheet. The h+ and ·O2 - species played important roles in RhB degradation under visible-light. A possible Z-scheme mechanism is proposed over the Ag3PO4/GO/NiFe2O4 (8%) composite. This study might provide a promising visible light responsive photocatalyst for the photocatalytic degradation of organic dyes in wastewater.