Abstract
NO x can be efficiently removed by micro-nano bubbles coupling with Fe3+ and Mn2+, but the catalyst cannot be reused and the adsorption wastewater should be treated. This work developed a new technology that uses micro-nano bubbles and recyclable MFe2O4 to simultaneously remove NO x and SO2 from flue gas, and clarified the effectiveness and reaction mechanism. MFe2O4 (M = Mn, Zn, Cu, Ni and Co) prepared by a hydrothermal method was characterized. The results show that MFe2O4 can be activated to produce ˙OH which can accelerate the oxidation absorption of NO x . Compared with no catalyst, the NO x conversion rate increased from 32.85% to 83.88% in the NO x -SO2-MFe2O4-micro-nano bubble system, while the removal rate of SO2 can reach 100% at room temperature. The catalytic activities of MFe2O4 showed the following trend: CuFe2O4 > ZnFe2O4 > MnFe2O4 > CoFe2O4 > NiFe2O4. The results provide a new idea for the application of advanced oxidation processes in flue gas treatment.