Abstract
Two novel binuclear complexes of Pb(ii) were synthesized by reacting a 3-(2-pyridyl)-5-(4-methoxyphenyl)-1,2,4-triazine (PMPT) ligand with different anionic co-ligands (1: bromide, 2: acetate and isothiocyanate) in a 1 : 1 molar ratio of PMPT ligands to lead(ii) salts. The complexes, [Pb2(μ-PMPT)2Br4] (1) and [Pb2(μ-PMPT)2((μ-CH3COO)2(NCS)2] (2), were characterized using various physicochemical techniques such as CHN analysis, FT-IR spectroscopy, and 1H NMR spectroscopy. Additionally, their structures were determined using single-crystal X-ray diffraction. Based on the obtained structural parameters, complex 1 exhibited a PbN3Br2 environment, while complex 2 displayed a PbN4O3 environment, with holodirected and hemidirected coordination spheres, respectively. Within the crystal network of the complexes, there were interactions involving C-H⋯X (X: O, S, N) as well as π-π stacking. The Pb(ii) complexes were further investigated for their potential use as the emitting layer in organic light-emitting devices (OLEDs). The current-voltage and luminescence-voltage characteristics, as well as the electroluminescence (EL) properties of the complexes, were studied.