Control of the Induced Handedness of Helical Nanofilaments Employing Cholesteric Liquid Crystal Fields

利用胆甾型液晶场控制螺旋纳米丝的诱导手性

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作者:Ju-Yong Kim, Jae-Jin Lee, Jun-Sung Park, Yong-Jun Choi, Suk-Won Choi

Abstract

In this paper, a simple and powerful method to control the induced handedness of helical nanofilaments (HNFs) is presented. The nanofilaments are formed by achiral bent-core liquid crystal molecules employing a cholesteric liquid crystal field obtained by doping a rod-like nematogen with a chiral dopant. Homochiral helical nanofilaments are formed in the nanophase-separated helical nanofilament/cholesteric phase from a mixture with a cholesteric phase. This cholesteric phase forms at a temperature higher than the temperature at which the helical nanofilament in a bent-core molecule appears. Under such conditions, the cholesteric liquid crystal field acts as a driving force in the nucleation of HNFs, realizing a perfectly homochiral domain consisting of identical helical nanofilament handedness.

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