Abstract
To switch the over-reliance on fossil-based resources, curb environmental quality deterioration, and promote the use of renewable fuels, much attention has recently been directed toward the implementation of sustainable and environmentally benign 'waste-to-energy' technology exploiting a clean, inexhaustible, carbon-neutral, and renewable energy source, namely agricultural biomass. From this perspective, anaerobic co-digestion (AcoD) technology emerges as a potent and plausible approach to attain sustainable energy development, foster environmental sustainability, and, most importantly, circumvent the key challenges associated with mono-digestion. This review article provides a comprehensive overview of AcoD as a biochemical valorization pathway of crop residues and livestock manure for biogas production. Furthermore, this manuscript aims to assess the different biotic and abiotic parameters affecting co-digestion efficiency and present recent advancements in pretreatment technologies designed to enhance feedstock biodegradability and conversion rate. It can be concluded that the substantial quantities of crop residues and animal waste generated annually from agricultural practices represent valuable bioenergy resources that can contribute to meeting global targets for affordable renewable energy. Nevertheless, extensive and multidisciplinary research is needed to evolve the industrial-scale implementation of AcoD technology of livestock waste and crop residues, particularly when a pretreatment phase is included, and bridge the gap between small-scale studies and real-world applications.