Abstract
Electrode modification has been one of the most active areas of interest in electrochemistry research. Hence, the investigation of the effects of chemically and electrochemically modified GCE nano-films on the NPs electrochemical properties. The electrochemistry of nano-films of Ag NPs, Au NPs and bimetallic Ag-Au (1:2) NPs of chemical citrate reduction synthesis drop coated (DCT) and electro-deposition method (EDP) are reported. The Chemically synthesized NPs were confirmed through FT-IR, UV-visible, XRD and SEM techniques while electro-deposited NPs were ascertained by double-pulsed chrono-amperometry and electrochemical impedance spectroscopy (EIS). The nano films; GCE/Ag NPs, GCE/Au NPs and GCE/Ag-Ag (1:2) NPs in 0.1 M HCl supporting electrolyte were studied via Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV) techniques. Generally the DCT nano films were electrochemically superior to the EDP film in terms of current intensities and GCE/Ag-Au (1:2) NPs showed enhanced α (0.019), k s (0.01 s-1), Q (3.6 × 10-9 C), Γ (5.3 × 10-13molescm-2) and D (1.31 × 10-1 cm2s-1), indicating better physicochemical properties for possible sensing applications compared to electro-deposited GCE nano-films.